Raman Spectroscopy of Arsenolite: Crystalline Cubic As4O6

Scott Kirkby; Sean J. Gilliam; Clifton N. Merrow; James O. Jensen; Daniel Zeroka; Ajit Banerjee

Raman Spectroscopy of Arsenolite: Crystalline Cubic As4O6

Scott Kirkby
, Sean J. Gilliam
, Clifton N. Merrow
, James O. Jensen
, Daniel Zeroka
, Ajit Banerjee

Department of Chemistry

University of Missouri - Rolla
U.S. Army Edgewood Chemical and Biological Center
Lehigh University

Research output: Contribution to conference › Presentation

Abstract

The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As2O3, has been found to have adamantanoid As4O6 molecules occupying the Td lattice sites. The complete Raman spectrum of arsenolite is reported. The previously unseen Eg mode has been found at 443cm-1. Further, there is additional support for the assignment of the 415cm-1 mode as T2g.

Original language	American English
State	Published - Sep 1 2005
Event	230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization - Washington, DC Convention Center Duration: Sep 1 2005 → …

Conference

Conference	230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization
Period	9/1/05 → …

Keywords

arsenolite
as4o6
crystalline
cubic
inorganic chemistry
raman spectroscopy

Disciplines

Physical Sciences and Mathematics
Chemistry
Inorganic Chemistry

Cite this

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title = "Raman Spectroscopy of Arsenolite: Crystalline Cubic As4O6",

abstract = " The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As2O3, has been found to have adamantanoid As4O6 molecules occupying the Td lattice sites. The complete Raman spectrum of arsenolite is reported. The previously unseen Eg mode has been found at 443cm-1. Further, there is additional support for the assignment of the 415cm-1 mode as T2g.",

keywords = "arsenolite, as4o6, crystalline, cubic, inorganic chemistry, raman spectroscopy",

author = "Scott Kirkby and Gilliam, \{Sean J.\} and Merrow, \{Clifton N.\} and Jensen, \{James O.\} and Daniel Zeroka and Ajit Banerjee",

note = "The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As 2O 3, has been found to have adamantanoid As 4O 6 molecules occupying the T d lattice sites. The complete Raman spectrum of arsenolite is reported. Gilliam, S. J., Merrow, C. N., Kirkby, S. J., Jensen, J. O., Zeroka, D., \& Banerjee, A. (2005, September 1). Raman spectroscopy of arsenolite: Crystalline cubic As4O6. Lecture presented at The 230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization, Washington DC Convention Center. Retrieved from http://oasys2.confex.com/acs/230nm/techprogram/P869651.HTM; 230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization ; Conference date: 01-09-2005",

year = "2005",

month = sep,

day = "1",

language = "American English",

}

TY - CONF

T1 - Raman Spectroscopy of Arsenolite: Crystalline Cubic As4O6

AU - Kirkby, Scott

AU - Gilliam, Sean J.

AU - Merrow, Clifton N.

AU - Jensen, James O.

AU - Zeroka, Daniel

AU - Banerjee, Ajit

N1 - The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As 2O 3, has been found to have adamantanoid As 4O 6 molecules occupying the T d lattice sites. The complete Raman spectrum of arsenolite is reported. Gilliam, S. J., Merrow, C. N., Kirkby, S. J., Jensen, J. O., Zeroka, D., & Banerjee, A. (2005, September 1). Raman spectroscopy of arsenolite: Crystalline cubic As4O6. Lecture presented at The 230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization, Washington DC Convention Center. Retrieved from http://oasys2.confex.com/acs/230nm/techprogram/P869651.HTM

PY - 2005/9/1

Y1 - 2005/9/1

N2 - The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As2O3, has been found to have adamantanoid As4O6 molecules occupying the Td lattice sites. The complete Raman spectrum of arsenolite is reported. The previously unseen Eg mode has been found at 443cm-1. Further, there is additional support for the assignment of the 415cm-1 mode as T2g.

AB - The group V oxides comprise a varied and diverse set of inorganic chemistry. Of particular interest are those that form adamantanoid cage compounds. Arsenolite, cubic crystalline As2O3, has been found to have adamantanoid As4O6 molecules occupying the Td lattice sites. The complete Raman spectrum of arsenolite is reported. The previously unseen Eg mode has been found at 443cm-1. Further, there is additional support for the assignment of the 415cm-1 mode as T2g.

KW - arsenolite

KW - as4o6

KW - crystalline

KW - cubic

KW - inorganic chemistry

KW - raman spectroscopy

UR - http://oasys2.confex.com/acs/230nm/techprogram/P869651.HTM

M3 - Presentation

T2 - 230th ACS National Meeting, Division of Inorganic Chemistry on Materials: Synthesis and Characterization

Y2 - 1 September 2005

ER -

Raman Spectroscopy of Arsenolite: Crystalline Cubic As4O6

Abstract

Conference

Keywords

Disciplines

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